You know many of the decisions we make rationally are motivated by more primal instincts as well. I, as many others do, go to work so that I may provide food and shelter to myself and my loved ones.
If I didn't have children and didn't want to have sex I most likely wouldnt work. I have often thought I would be just as happy being an itinerant drunk if I had no desire for sex or children.
Anyway now that I have children I feel a moral compunction to keep employed and providing them with food and shelter, until they are at least 18, whereupon I may reconsider becoming an itinerant drunk.
While having a family to support can give extra motivation to work, it's hardly the only reason people work. And no, the other reason isn't just to have enough cash for booze, either. First couple months with no work is pretty nice, basically like a long vacation where you can do a lot of fun stuff and have few worries. Come the third month you'll be getting bored with the routine, even if you change around hobbies, though things are still going pretty well. Come the fourth month You'll be wanting something to do, and finding that your hobbies just aren't bringing nearly as much satisfaction as they used to. Come the fifth month you'll be wanting just about anything to do, being disinterested in your hobbies, bored as fuck (and if fucking is what you spent your time doing even that will be boring), and basically finding little point in things. Given enough time you'll eventually flatten out at "meh," regularly being bored, loosing interest in different hobbies that you've already spent an enormous amount of time on because it was all you had to do, and otherwise grudgingly admitting your life is now very dull and that you wish there was some obligation to add variety and life back into your, well, life. I speak from experience on that, and pretty much everyone else I've talked to who's gone through such periods of nothing to do have given similar stories of how it goes.